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11月, 2016の投稿を表示しています
Article Previous Article   Next Article   Articles ASAP Reactivity of a Cobalt(III)–Hydroperoxo Complex in Electrophilic Reactions Bongki Shin † ,  Kyle D. Sutherlin ‡ ,  Takehiro Ohta § ,  Takashi Ogura § ,  Edward I. Solomon * ‡ ∥ , and  Jaeheung Cho * † †  Department of Emerging Materials Science,  DGIST , Daegu 42988,  Korea ‡  Department of Chemistry,  Stanford University , Stanford, California 94305,  United States §  Picobiology Institute, Graduate School of Life Science,  University of Hyogo , RSC-UH LP Center, Hyogo 679-5148,  Japan ∥  Stanford Synchrotron Radiation Laboratory,  Stanford Linear Accelerator Center , Menlo Park, California 94025,  United States Inorg. Chem. , Article ASAP DOI:  10.1021/acs.inorgchem.6b02288 Publication Date (Web): November 15, 2016 Copyright © 2016 American Chemical Society *E-mail:  edward.solomon@stanford.edu ., *E-mail:  jaeheung@dgist.ac.kr . Synopsis A

Why copper is preferred over iron for oxygen activation and reduction in haem-copper oxidases

Ambika Bhagi-Damodaran 1 , Matthew A. Michael 2 , Qianhong Zhu 3 , Julian Reed 4 , Braddock A. Sandoval 1 , Evan N. Mirts 5 , Saumen Chakraborty 1 , Pierre Moënne-Loccoz 3 * , Yong Zhang 2 * and Yi Lu 1,4,5 *    Nature Chemistry (2016)       doi:10.1038/nchem.2643 Received              05 April 2016 Accepted             09 September 2016 Published online   07 November 2016   http://www.nature.com/nchem/journal/vaop/ncurrent/pdf/nchem.2643.pdf Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois, USA. 2 Department of Biomedical Engineering, Chemistry, and Biological Sciences, Stevens Institute of Technology, Hoboken, New Jersey, USA. 3 Division of Environmental & Biomolecular Systems, Institute of Environmental Health, Oregon Health & Science University 4 Department of Biochemistry, University of Illinois at Urbana-Cha