Itoh Group Literature Review

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Isolation of a (Dinitrogen)Tricopper(I) Complex

Leslie J. Murray * † , Walter W. Weare ‡ , Jason Shearer § , Alyssa D. Mitchell † , and Khalil A. Abboud † † Department of Chemistry, Center for Catalysis, University of Florida , Gainesville, Florida 32611, United States ‡ Department of Chemistry, North Carolina State University , Raleigh, North Carolina 27695, United States § Department of Chemistry, University of Nevada , Reno, Reno, Nevada 89557, United States J. Am. Chem. Soc. , Article ASAP DOI: 10.1021/ja506445d Publication Date (Web): September 19, 2014 Copyright © 2014 American Chemical Society murray@chem.ufl.edu Abstract Reaction of a tris(β-diketimine) cyclophane, H 3 L , with benzyl potassium followed by [Cu(OTf)] 2 (C 6 H 6 ) affords a tricopper(I) complex containing a bridging dinitrogen ligand. rRaman (ν N–N = 1952 cm –1 ) and 15 N NMR (δ = 303.8 ppm) spectroscopy confirm ...

Iron and Chromium Complexes Containing Tridentate Chelates Based on Nacnac and Imino- and Methyl-Pyridine Components: Triggering C–X Bond Formation

Inorganic Chemistry: Latest Articles (ACS Publications) by Wesley D. Morris, Peter T. Wolczanski, Jörg Sutter, Karsten Meyer, Thomas R. Cundari and Emil B. Lobkovsky / 16h // keep unread // hide // preview Inorganic Chemistry DOI: 10.1021/ic500807y Visit Website

Redox Chemistry of Nickel(II) Complexes Supported by a Series of Noninnocent β-Diketiminate Ligands

髙市さんの置き土産 Article Previous Article Next Article Articles ASAP Redox Chemistry of Nickel(II) Complexes Supported by a Series of Noninnocent β-Diketiminate Ligands ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF [2349 KB] PDF w/ Links [468 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx June Takaichi † , Yuma Morimoto † , Kei Ohkubo † , Chizu Shimokawa ‡ , Takayuki Hojo § , Seiji Mori * § , Haruyasu Asahara , Hideki Sugimoto † , Nobutaka Fujieda † , Nagatoshi Nishiwaki , Shunichi Fukuzumi † , and Shinobu Itoh * † † Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University , 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan ‡ Department of Medic...

Iron Complexes Derived from {nacnac-(CH2py)2}− and {nacnac-(CH2py)(CHpy)}n Ligands: Stabilization of Iron(II) via Redox Noninnocence

Valerie A. Williams † , Peter T. Wolczanski * † , Jörg Sutter ‡ , Karsten Meyer ‡ , Emil B. Lobkovsky † , and Thomas R. Cundari § † Baker Laboratory, Department of Chemistry & Chemical Biology, Cornell University , Ithaca, New York 14853, United States ‡ Department of Chemistry & Pharmacy, University of Erlangen-Nuremberg , Egerlandstrasse 1. D-91058 Erlangen, Germany § Department of Chemistry, Center for Advanced Scientific Computing and Modeling (CASCaM), University of North Texas , Box 305070, Denton, Texas 76203-5070, United States Inorg. Chem. , Article ASAP DOI: 10.1021/ic5001123 Publication Date (Web): April 24, 2014 Copyright © 2014 American Chemical Society *E-mail: ptw2@cornell.edu . Fax: 607 255 4173 . Synopsis Nanac-based tetradentate chelates, {nacnac-(CH2py)2}− ({nn(PM)2}−) and {nacnac-(CH2py)(CHpy)}n ({nn(PM)...

Synthesis and Thermal Decomposition of a Pyridylene-Bridged bis-ß-Diketiminate Magnesium Hydride Cluster

Sjoerd Harder , Jan Spielmann and Julia Intemann Received 19th March 2014 , Accepted 11th April 2014 First published on the web 14th April 2014 Reaction of PYR-(MgnBu)2, in which PYR is 2,6-[(DIPP)NC(Me)CHC(Me)N-]2-pyridine and DIPP is 2,6-iPr2-phenyl, with (DIPP)NH2BH3 gave PYR-[MgNH(DIPP)BH3]2 (56%) which was characterized by crystal structure determination. Addition of THF resulted in ß-H elimination and formation of PYR-[MgNH(DIPP)BH3](MgH)∙THF (57%), likewise characterized by crystal structure determination. Conversion of the second amidoborane anion in Hˉ could not be achieved. Reaction of PYR-(MgnBu)2 with PhSiH3 gave PYR-(MgH)2 which crystallized as a dimer. The structure of [PYR-(MgH)2]2 shows a 8-membered ring of Mg2+ and Hˉ ions. Thermal decomposition at 130 °C releases one equivalent of H2, i.e. 50% of the expected value. Nucleophilic attack at the para-position and reduction of the pyridylene bridge might explain reduced H2 release. ...

C–H and C–O bond activation with a rhodium(I) β-diiminate complex

Nicolle N. P. Langer , a Gurmeet Singh Bindra b and Peter H. M. Budzelaar * b Show Affiliations Dalton Trans. , 2014, Advance Article DOI: 10.1039/C4DT00309H Received 29 Jan 2014, Accepted 26 Mar 2014 First published online 03 Apr 2014 | | Share on citeulike | Share on facebook | Share on twitter | | More PDF Rich HTML Send PDF to Kindle Download Citation BibTex EndNote MEDLINE ProCite ReferenceManager RefWorks RIS Request Permissions Abstract Cited by Related Content Metrics Complex LRh(COE) [L = (2,6-Me 2 C 6 H 3 NCMe) 2 CH; COE = cyclooctene] reacts with oxirane, methyloxirane and 2,2-dimethyloxirane to eventually produce LRh(COE)(CO) and alkane (methane, ethane, propane). This reaction and other aspects of the reactivity of the “LRh” fragment (hydrogenation of olefins and benzene) ...

Well-Defined Four-Coordinate Iron(II) Complexes For Intramolecular Hydroamination of Primary Aliphatic Alkenylamines†

Dr. Elise Bernoud ‡ , Dr. Pascal Oulié ‡ , Dr. Régis Guillot, Dr. Mohamed Mellah and Dr. Jérôme Hannedouche * Article first published online: 1 APR 2014 DOI: 10.1002/anie.201402089 © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Keywords: alkenes; amines; homogeneous catalysis; hydroamination; iron Abstract Despite the growing interest in iron catalysis and hydroamination reactions, iron-catalyzed hydroamination of unprotected primary aliphatic amines and unactivated alkenes has not been reported to date. Herein, a novel well-defined four-coordinate β-diketiminatoiron(II) alkyl complex is shown to be an excellent precatalyst for the highly selective cyclohydroamination of primary aliphatic alkenylamines at mild temperatures (70–90 °C). Both empirical kinetic analyses and the reactivity of an isolated iron(II) amidoalkene dimer, [LFe(NHCH 2 CPh 2 CH 2 CH CH 2 )] 2 favor a stepwise σ-insertive mechanism that entails m...

A Two-Coordinate Manganese(0) Complex with an Unsupported Mn–Mg Bond: Allowing Access to Low Coordinate Homo- and Heterobimetallic Compounds

Communication ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF [681 KB] PDF w/ Links [254 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx Jamie Hicks † , Chad E. Hoyer ‡ , Boujemaa Moubaraki † , Giovanni Li Manni ‡ , Emma Carter § , Damien M. Murphy § , Keith S. Murray † , Laura Gagliardi ‡ , and Cameron Jones * † † School of Chemistry, Monash University , Melbourne, Victoria, 3800, Australia ‡ Department of Chemistry and Minnesota Supercomputing Institute, University of Minnesota 207 Pleasant St, SE Minneapolis, Minnesota 55455-0431, United States § School of Chemistry, Cardiff University , Cardiff, CF10 3AT, United Kingdom J. Am. Chem. Soc. , Article ASAP DOI: 10.1021/ja5021348 Publication Date (Web): Mar...