1 Inorganic Chemistry: Latest Articles (ACS Publications) by Logan J. Giles, Christian Ruppelt, Jing Yang, Ralf R. Mendel, Florian Bittner and Martin L. Kirk / 11h // keep unread // hide // preview Inorganic Chemistry DOI: 10.1021/ic5015863 Visit Website
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Journal of the American Chemical Society: Latest Articles (ACS Publications) by Yunbo Jiang, Takahiro Hayashi, Hirotoshi Matsumura, Loi H. Do, Amit Majumdar, Stephen J. Lippard and Pierre Moënne-Loccoz / 8h // keep unread // hide // preview Journal of the American Chemical Society DOI: 10.1021/ja504343t Visit Website
Angewandte Chemie International Edition by Fanzhi Yang, Karsten Rauch, Katharina Kettelhoit, Lutz Ackermann / 2h // keep unread // hide // preview Abstract Versatile ruthenium(II) complexes allow for site-selective CH oxygenations with weakly-coordinating aldehydes. The challenging CH functionalizations proceed with high chemoselectivity by rate-determining CH metalation. The new method features an ample substrate scope, which sets the stage for the step-economical preparation of various bioactive heterocycles. The weakest link : Challenging aryl CH oxygenations with very weakly coordinating aldehydes proceed chemoselectively in the presence of versatile ruthenium(II) catalysts under mild reaction conditions. This transformation features an ample substrate scope and excellent positional selectivity. Visit Website
Electrocatalytic O2 Reduction by Monolayer of Hemin: Role of pKa of Distal and Proximal Oxygen of a FeIII-OOH Species in Determining Reactivity
Chem. Commun. , 2014, Accepted Manuscript DOI : 10.1039/C4CC03886J, Communication Sohini Mukherjee, Sabyasachi Bandyopadhyay, Sudipta Chatterjee, Abhishek Dey Investigation of the proton coupled electron transfer steps involved in electrocatalytic ORR by Hemin modified electrodes allow determination of pK a 's of the proximal and distal oxygen atoms of a rate...
Homogeneous Photochemical Water Oxidation by Biuret-Modified Fe-TAML: Evidence of FeV(O) Intermediate
Chakadola Panda, Joyashish Debgupta, David Díaz Díaz, Kundan K. Singh, Sayam Sen Gupta, and Basab B. Dhar Articles ASAP (As Soon As Publishable) Publication Date (Web): August 13, 2014 ( Article ) DOI: 10.1021/ja503753k Figure 1 of 7
Behavior of anionic molybdenum(IV, VI) and tungsten(IV, VI) complexes containing bulky hydrophobic dithiolate ligands and intramolecular NH[round bullet, filled][round bullet, filled][round bullet, filled]S hydrogen bonds in nonpolar solvents
RSC - Dalton Trans. latest articles by Yuki Hasenaka Dalton Trans. , 2014, Accepted Manuscript DOI : 10.1039/C4DT01646G, Paper Yuki Hasenaka, Taka-aki Okamura, Miki Tatsumi, Naoya Inazumi, Kiyotaka Onitsuka Visit Website
Back Cover: Oxygenation by Ruthenium Monosubstituted Polyoxotungstates in Aqueous Solution: Experimental and Computational Dissection of a Ru(III)–Ru(V) Catalytic Cycle (Chem. Eur. J. 35/2014)
おもしろいカバーです。それだけですが。 Chemistry - A European Journal by Andrea Sartorel, Pere Miró, Mauro Carraro, Serena Berardi, Olga Bortolini, Alessandro Bagno, Carles Bo , Marcella Bonchio / 11h // keep unread // hide // preview Polyoxometalate ligands play a key role in facilitating a ruthenium catalyst access to a high-valent reactive state in aerobic oxidation in water. In their Full Paper on page 10932 ff. , C. Bo, M. Bonchio et al. show that the reaction involves novel ruthenium–peroxo and oxene intermediates embedded within a totally inorganic POM environment. This breakthrough perspective is one the central themes of the European COST action entitled Polyoxometalate Chemistry for Molecular Nanoscience (PoCheMoN). The cover art is inspired by the popular fantasy game (Pokémon).
Iron(III) complexes of tripodal tetradentate 4N ligands as functional models for catechol dioxygenases: the electronic vs. steric effect on extradiol cleavage
RSC - Dalton Trans. latest articles by Mani Balamurugan Dalton Trans. , 2014, Advance Article DOI : 10.1039/C3DT52145A, Paper Mani Balamurugan, Prabha Vadivelu, Mallayan Palaniandavar The extradiol ( E ) to intradiol ( I ) product selectivity ( E / I , 0.1-2.0) depends upon the asymmetry in bidentate coordination of catecholate, as determined by the stereoelectronic properties of the ligands. Visit Website
Heterolytic cleavage of H2 by bifunctional manganese(I) complexes: impact of ligand dynamics, electrophilicity, and base positioning
RSC - Chem. Sci. latest articles by Elliott B. Hulley / 6d // keep unread // hide // preview +TAG Chem. Sci. , 2014, Advance Article DOI : 10.1039/C4SC01801J, Edge Article Elliott B. Hulley, Monte L. Helm, R. Morris Bullock A balance of metal electrophilicity and ligand steric influences is required for facile, reversible H-H heterolytic cleavage in Mn complexes with pendant amines. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry Visit Website
Stahlらによる、アルコールの空気酸化の反応機構に関する詳細。銅錯体にアルコールとTEMPOが配位した三元錯体中で、競争的なH•トランスファーが進行するとしている。 Journal of the American Chemical Society: Latest Articles (ACS Publications) by Bradford L. Ryland, Scott D. McCann, Thomas C. Brunold and Shannon S. Stahl / 6d // keep unread // hide // preview Journal of the American Chemical Society DOI: 10.1021/ja5070137 Visit Website
Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions
Stahlらによる、新しい酸素を利用した反応系の報告。コバルト錯体を酸素のアクティベーションに使っている。 Journal of the American Chemical Society: Latest Articles (ACS Publications) by Alison E. Wendlandt and Shannon S. Stahl / 1d // keep unread // hide // preview Journal of the American Chemical Society DOI: 10.1021/ja506546w Visit Website
Journal of the American Chemical Society: Latest Articles (ACS Publications) by George E. Cutsail III, Benjamin W. Stein, Deepak Subedi, Jeremy M. Smith, Martin L. Kirk and Brian M. Hoffman / 1d // keep unread // hide // preview Journal of the American Chemical Society DOI: 10.1021/ja505403j Visit Website
Spectroscopic Characterization and Reactivity Studies of a Mononuclear Nonheme Mn(III)–Hydroperoxo Complex
Journal of the American Chemical Society: Latest Articles (ACS Publications) by Hee So, Young Jun Park, Kyung-Bin Cho, Yong-Min Lee, Mi Sook Seo, Jaeheung Cho, Ritimukta Sarangi and Wonwoo Nam / 15h // keep unread // hide // preview Journal of the American Chemical Society DOI: 10.1021/ja506275q Visit Website
Nicholas Cox 1 , * , Marius Retegan 1 , Frank Neese 1 , Dimitrios A. Pantazis 1 , Alain Boussac 2 , Wolfgang Lubitz 1 , * + Author Affiliations 1 Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, D-45470 Mülheim an der Ruhr, Germany. 2 Institut de Biologie et de Technologies de Saclay, CNRS UMR 8221, Commissariat à l’Énergie Atomique (CEA) Saclay, 91191 Gif-sur-Yvette, France. ↵ * Corresponding author. E-mail: nicholas.cox@cec.mpg.de (N.C.); wolfgang.lubitz@cec.mpg.de (W.L.) ABSTRACT EDITOR'S SUMMARY The photosynthetic protein complex photosystem II oxidizes water to molecular oxygen at an embedded tetramanganese-calcium cluster. Resolving the geometric and electronic structure of this cluster in its highest metastable catalytic state (designated S 3 ) is a prerequisite for understanding the mechanism of O-O bond formation. Here, multifrequency, multidimensional magnetic resonance spectroscopy reveals that all four mangan