Itoh Group Literature Review

Communication ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF  [681 KB] PDF w/ Links [254 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx Jamie Hicks   † ,  Chad E. Hoyer   ‡ ,  Boujemaa Moubaraki   † ,  Giovanni Li Manni   ‡ ,  Emma Carter   § , Damien M. Murphy   § ,  Keith S. Murray   † ,  Laura Gagliardi   ‡ , and  Cameron Jones   * † †  School of Chemistry,  Monash University , Melbourne, Victoria, 3800,  Australia ‡  Department of Chemistry and Minnesota Supercomputing Institute,  University of Minnesota  207 Pleasant St, SE Minneapolis, Minnesota 55455-0431, United States §  School of Chemistry,  Cardiff University , Cardiff, CF10 3AT,  United Kingdom J. Am. Chem. Soc. , Article ASAP DOI:  10.1021/ja5021348 Publication Date (Web): March 24, 2014 Copyright © 2014 American Chemical Society cameron.jones@monash.edu Section: Inorganic Chemicals and Reactions

酵素中とモデル錯体では、同じリガンドでもバインドの角度が違うということを論文にしている。なんで？という所の考察とか、ここからなにができるの？というのは正直弱いとおもうけど、着眼点はファインだと思います。こういう配位角や距離が、最も安定な位置関係からずれる事による現象は、個人的には非常に興味深いです。 イントロに、" The results not only show the utility but also the limitations of bioinorganic modeling while highlighting the subtle influence of active site structure on metal–ligand bonding. Such subtle effects on coordination chemistry are not readily predicted by current paradigms in bioinorganic chemistry and, consequently, are not implemented in standard drug design efforts directed at metalloproteins. " と、ありますが、この辺りは伊東研としても切り込めるところではないでしょうか。 Article ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF  [2731 KB] PDF w/ Links [361 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx David P. Martin   † ,  Patrick G. Blachly   † ,  Amy R. Marts ‡ ,  Tessa M. Woodruff   ‡ ,  César A. F. de Oliveira   ,  J. Andrew McCammon   †

Article ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF  [1349 KB] PDF w/ Links [346 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx Bren E. Cole   † ,  Jeffrey P. Wolbach   † ,  William G. Dougherty   ,  Jr. ‡ ,  Nicholas A. Piro   ‡ ,  W. Scott Kassel ‡ , and  Christopher R. Graves   * † †  Department of Chemistry & Biochemistry,  Albright College , 13th & Bern Street, Reading, Pennsylvania 19612,  United States ‡  Department of Chemistry,  Villanova University , 800 Lancaster Avenue, Villanova, Pennsylvania 19085, United States Inorg. Chem. , Article ASAP DOI:  10.1021/ic5003989 Publication Date (Web): March 24, 2014 Copyright © 2014 American Chemical Society *E-mail:  cgraves@alb.edu . Synopsis Aluminum-α-diimine complexes have been prepared in both the −1 and −2 oxidation states of the ligand. The complexes have been characterized structurally, spectrosc

Article ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF  [1017 KB] PDF w/ Links [495 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx Josep Llaveria   ,  Álvaro Beltrán   ‡ ,  W. M. C. Sameera † ,  Abel Locati   † ,  M. Mar Díaz-Requejo   * ‡ ,  M. Isabel Matheu   * ,  Sergio Castillón   * ,  Feliu Maseras   * † § , and  Pedro J. Pérez   * ‡  Departament de Química Analítica i Química Orgànica, Facultat de Química,  Universitat Rovira i Virgili , C/Marcel·lí Domingo s/n, 43007 Tarragona, Spain ‡  Laboratorio de Catálisis Homogénea, Unidad Asociada al CSIC, CIQSO-Centro de Investigación en Química Sostenible and Departamento de Química y Ciencia de los Materiales,  Universidad de Huelva , Campus de El Carmen 21007 Huelva,  Spain †  Institute of Chemical Research of Catalonia, ICIQ, Av. Països Catalans 16, 43007 Tarragona,  Spain §  Departament de Química,  Universitat Autònoma de B

NATURE CHEMISTRY  |  ARTICLE Print Email Share/bookmark Time-resolved observations of water oxidation intermediates on a cobalt oxide nanoparticle catalyst Miao Zhang , Moreno de Respinis &  Heinz Frei Affiliations Contributions Corresponding author Nature Chemistry   6 ,   362–367   (2014)   doi:10.1038/nchem.1874 Received   16 November 2013  Accepted   14 January 2014  Published online   23 February 2014 Article tools PDF Citation Reprints Rights & permissions Article metrics Abstract Abstract •   Main •   Results and discussion •   Conclusions •   Methods •   References •   Acknowledgements •   Author information •   Supplementary information In any artificial photosynthetic system, the oxidation of  water  to molecular  oxygen  provides the electrons needed for the reduction of protons or  carbon dioxide  to a fuel. Understanding how this four-electron reaction works in detail is important for the devel

Article Effect of Ligand Substituent Coordination on the Geometry and the Electronic Structure of Cu(II)-Diradical Complexes ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF  [881 KB] PDF w/ Links [303 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx Richa Rakshit   † ,  Samir Ghorai   † ,  Soumava Biswas   ‡ , and  Chandan Mukherjee   * † †  Department of Chemistry,  Indian Institute of Technology , Guwahati 781039, Assam,  India ‡   Indian Institute of Science Education and Research Bhopal , Bhopal 462023, Madhya Pradesh,  India Inorg. Chem. , Article ASAP DOI:  10.1021/ic402612v Publication Date (Web): March 21, 2014 Copyright © 2014 American Chemical Society *E−mail:  cmukherjee@iitg.ernet.in . Synopsis The extent of interaction between the Cu(II) center and the donor atom that belongs to a substituent attached at the ortho position of the aniline moiety of 2-a