Itoh Group Literature Review

Edge Article Conversion of High-Spin Iron(III)-Alkylperoxo to Iron(IV)-Oxo Species via O-O Bond Homolysis in Nonheme Iron Models Seungwoo Hong ,     Yong-Min Lee ,     Kyung-Bin Cho ,     Mi Sook Seo ,   Dayoung Song ,     Jihae Yoon ,     Ricardo Garcia-Serres ,   Martin Clémancey ,     Takashi Ogura ,     Woonsup Shin ,   Jean-Marc Latour  and     Wonwoo Nam    Chem. Sci. , 2013, Accepted Manuscript DOI:  10.1039/C3SC52236A Received 09 Aug 2013, Accepted 17 Sep 2013 First published online 18 Sep 2013 | | Share on citeulike | Share on facebook | Share on twitter | | More PDF Rich HTML    Send PDF to Kindle Download Citation BibTex   EndNote   MEDLINE   ProCite   ReferenceManager   RefWorks   RIS   Request Permiss...

Bidentate Ligands on Osmium(VI) Nitrido Complexes Control Intracellular Targeting and Cell Death Pathways ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF  [1035 KB] PDF w/ Links [237 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx Kogularamanan Suntharalingam   † ,  Timothy C. Johnstone   † ,  Peter M. Bruno   ‡ ,  Wei Lin   † ,  Michael T. Hemann   ‡ , and  Stephen J. Lippard   * † †  Department of Chemistry,  Massachusetts Institute of Technology , Cambridge, Massachusetts 02139,  United States ‡  The Koch Institute for Integrative Cancer Research, Massachusetts Institute of Technology , Cambridge, Massachusetts 02139,  United States J. Am. Chem. Soc. , Article ASAP DOI:  10.1021/ja4075375 Publication Date (Web): August 20, 2013 Copyright © 2013 American Chemical Society lippard@mit....

Communication Oxidation of Water by a Nonheme Diiron(IV) Complex via Proton-Coupled Electron Transfer Dong Wang  and     Lawrence Que Jr.    Chem. Commun. , 2013, Accepted Manuscript DOI:  10.1039/C3CC46391E Received 21 Aug 2013, Accepted 25 Sep 2013 First published online 26 Sep 2013 | | Share on citeulike | Share on facebook | Share on twitter | | More PDF Rich HTML    Send PDF to Kindle Download Citation BibTex   EndNote   MEDLINE   ProCite   ReferenceManager   RefWorks   RIS   Request Permissions Abstract Cited by Related Content   A high-potential nonhaem (μ-oxo)diiron(IV) complex was found to oxidize water to hydroxyl radical via PCET, instead of forming an O–O bond. The rate-determining step requires a second water molecule, proposed to act as a base to promote proton transfer. This work shows that additional facto...

THF Exchange and Molecular Dynamics in the Series (BDI)MgX(THF), Where X = Bu n , NEt 2 , and OBu t  and BDI = 2-[(2,6-Diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF  [923 KB] PDF w/ Links [430 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx Malcolm H. Chisholm   * ,  Kittisak Choojun   ,  Albert S. Chow   ,  Gideon Fraenkel   * , and  Judith C. Gallucci Department of Chemistry and Biochemistry,  The Ohio State University , 100 West 18th Avenue, Columbus, Ohio 43210,  United States Inorg. Chem. , Article ASAP DOI:  10.1021/ic401559b Publication Date (Web): September 25, 2013 Copyright © 2013 American Chemical Society *E-mail:  chisholm@chemistry.ohio-state.edu ., *E-mail: fraenkel@mps.ohio-state.edu . Abstract The complexes (BDI...

Efficient water oxidation catalyzed by homogeneous cationic cobalt porphyrins with critical roles for the buffer base Dong Wang  and   John T. Groves PNAS   2013  110  ( 39 )   15579 - 15584 ;  published ahead of print  September 9, 2013 , doi: 10.1073/pnas.1315383110 Abstract   Full Text (HTML)   Full Text (PDF)   Figures Only   Supporting Information Significance Efficient and scalable catalysts that mediate the interconversion of electrical and chemical energy are essential to the future world economy. Central to this challenge are robust systems that can split water into its elements, hydrogen and oxygen, with minimal cost. In this article, we describe the discovery and characterization of an efficient, single-site homogeneous water oxidation catalyst based on a cationic cobalt-porphyrin system. Important roles of the buffer base in this catalysis are also described. Our results shed light on the d...