Itoh Group Literature Review

Inorganic Chemistry: Latest Articles (ACS Publications)  by Lucía Álvarez, Sebastián A. Suarez, Damian E. Bikiel, Julio S. Reboucas, Ines Batinić-Haberle, Marcelo A. Martí and Fabio Doctorovich  /   2d   //   keep unread   //   hide   //   preview Inorganic Chemistry DOI: 10.1021/ic5007082 Visit Website   +TAG

Inorganic Chemistry: Latest Articles (ACS Publications)  by Marzio Rancan, Jacopo Tessarolo, Maurizio Casarin, Pier Luigi Zanonato, Silvio Quici and Lidia Armelao  /   2d   //   keep unread   //   hide   //   preview Inorganic Chemistry DOI: 10.1021/ic500573e Visit Website   +TAG

Inorganic Chemistry: Latest Articles (ACS Publications)  by Machima Manowong, Baocheng Han, Thomas R. McAloon, Jianguo Shao, Ilia A. Guzei, Siyabonga Ngubane, Eric Van Caemelbecke, John L. Bear and Karl M. Kadish  /   2d   //   keep unread   //   hide   //   preview Inorganic Chemistry DOI: 10.1021/ic5007605 Visit Website   +TAG

Journal of the American Chemical Society: Latest Articles (ACS Publications)  by Jung Yoon Lee, Ryan L. Peterson, Kei Ohkubo, Isaac Garcia-Bosch, Richard A. Himes, Julia Woertink, Cathy D. Moore, Edward I. Solomon, Shunichi Fukuzumi and Kenneth D. Karlin  /   2d   //   keep unread   //   hide   //   preview Journal of the American Chemical Society DOI: 10.1021/ja503105b Visit Website

Angewandte Chemie International Edition  by Joan Serrano-Plana, Isaac Garcia-Bosch, Ryosuke Miyake, Miquel Costas, Anna Company  /   4d   //   keep unread   //   hide   //   preview Abstract The bis(μ-oxo)dicopper(III) species [Cu III 2 (μ-O) 2 (m-XYL MeAN )] 2+  ( 1 ) promotes the electrophilic ortho-hydroxylation–defluorination of 2-fluorophenolates to give the corresponding catechols, a reaction that is not accomplishable with a (η 2 :η 2 -O 2 )dicopper(II) complex. Isotopic labeling studies show that the incoming oxygen atom originates from the bis(μ-oxo) unit. Ortho-hydroxylation–defluorination occurs selectively in intramolecular competition with other ortho-substituents such as chlorine or bromine. O in, F out : [Cu III 2 (μ-O) 2 ( m -XYL MeAN )] 2+  is a bis(μ-oxo)dicopper(III) species and promotes the electrophilic  ortho -hydroxylation–defluorination of 2-fluoroph...

Mechanistic Insights into the Oxidation of Substituted Phenols via Hydrogen Atom Abstraction by a Cupric–Superoxo Complex ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF  [2073 KB] PDF w/ Links [579 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx Jung Yoon Lee   † ,  Ryan L. Peterson   † ,  Kei Ohkubo ‡ ,  Isaac Garcia-Bosch   † ,  Richard A. Himes   † ,  Julia Woertink   § ,  Cathy D. Moore   † ,  Edward I. Solomon * § ,  Shunichi Fukuzumi   * ‡ , and  Kenneth D. Karlin * † †  Department of Chemistry,  Johns Hopkins University , Baltimore, Maryland 21218,  United States ‡  Department of Material and Life Science, Graduate School of Engineering, and ALCA, Japan Science and Technology Agency (JST),  Osaka University , Suita, Osaka 565-0871,  Japan §  Department of Ch...

Communication Previous Article Next Article Articles ASAP A Multi-iron System Capable of Rapid N 2  Formation and N 2  Cleavage ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF  [735 KB] PDF w/ Links [254 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx K. Cory MacLeod   ,  David J. Vinyard   , and  Patrick L. Holland   * Department of Chemistry,  Yale University , 225 Prospect Street, New Haven, Connecticut 06520, United States J. Am. Chem. Soc. , Article ASAP DOI:  10.1021/ja505193z Publication Date (Web): July 8, 2014 Copyright © 2014 American Chemical Society patrick.holland@yale.edu Abstract The six-electron oxidation of two nitrides to N 2  is a key step of ammonia synthesis and decomposition reactions on surfaces. In molecular complexes, nitride coupling has been observed with terminal nitride...