高原子価パラジウム錯体
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† Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109,United States
‡ Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195, United States
§ School of Chemistry, University of Tasmania, Private Bag 75, Hobart, Tasmania 7001, Australia
J. Am. Chem. Soc., Article ASAP
DOI: 10.1021/ja412338k
Publication Date (Web): June 2, 2014
Copyright © 2014 American Chemical Society
Abstract
This article describes the high-yielding and selective oxidatively induced formation of ethane from mono-methyl palladium complexes. Mechanistic details of this reaction have been explored via both experiment and computation. On the basis of these studies, a mechanism involving methyl group transmetalation between PdII and PdIV interediates is proposed.
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