Generation, Characterization, and Reactivity of a CuII–Alkylperoxide/Anilino Radical Complex: Insight into the O–O Bond Cleavage Mechanism
Sayantan Paria † , Takehiro Ohta ‡ , Yuma Morimoto † , Takashi Ogura ‡ , Hideki Sugimoto † , Nobutaka Fujieda † , Kei Goto ¶ , Kaori Asano § , Takeyuki Suzuki § , and Shinobu Itoh * † † Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University , 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan ‡ Picobiology Institute, Graduate School of Life Science, University of Hyogo , RSC-UH LP Center, Koto 1-1-1, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan ¶ Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology , 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8551, Japan § Comprehensive Analysis Center, The Institute of Scientific and Industrial Research (ISIR), Osaka University , 8-1 Mihogaoka, Ibaraki, Osaka 567-0057, Japan J. Am. Chem. Soc. , Article ASAP DOI: 10.1021/jacs.5b04104 Publication Date (Web): August 20, 2015 Copyright © 2015 American Chemical Society...