スキップしてメイン コンテンツに移動

投稿

A 3-Fold-Symmetric Ligand Based on 2-Hydroxypyridine: Regulation of Ligand Binding by Hydrogen Bonding

Communication A 3-Fold-Symmetric Ligand Based on 2-Hydroxypyridine: Regulation of Ligand Binding by Hydrogen Bonding ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF  [691 KB] PDF w/ Links [210 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx Cameron M. Moore   ,  David A. Quist   ,  Jeff W. Kampf   , and  Nathaniel K. Szymczak   * Department of Chemistry,  University of Michigan , Ann Arbor, Michigan 48109,  United States Inorg. Chem. , Article ASAP DOI:  10.1021/ic5003594 Publication Date (Web): March 21, 2014 Copyright © 2014 American Chemical Society *E-mail:  nszym@umich.edu . Synopsis A tripodal ligand based on 2-hydroxypyridine is presented. Cu−Cl adducts of H3thpa with CuI and CuII provide complexes featuring highly directed, intramolecular hydrogen-bonding interactions. An upper limit for the hydroge...
Article Reusable Oxidation Catalysis Using Metal-Monocatecholato Species in a Robust Metal–Organic Framework ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF  [2166 KB] PDF w/ Links [480 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx Honghan Fei   † ,  JaeWook Shin   ‡ ,  Ying Shirley Meng   ‡ , Mario Adelhardt   § ,  Jörg Sutter   § ,  Karsten Meyer   § , and  Seth M. Cohen   * † † Department of Chemistry and Biochemistry and ‡ Department of NanoEngineering,  University of California, San Diego , La Jolla, California 92093, United States §  Department of Chemistry and Pharmacy, Inorganic Chemistry,  Friedrich-Alexander University Erlangen − Nürnberg (FAU) , Egerlandstrasse 1, 91058 Erlangen, Germany J. Am. Chem. Soc. , Article ASAP DOI:  10.1021/ja411627z Publication Date (Web): March 5, 2...

Shunichi Fukuzumi

Author Profile You have full text access to this content Shunichi Fukuzumi Article first published online: 20 MAR 2014 DOI: 10.1002/anie.201400648 © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Issue Angewandte Chemie International Edition Early View (Online Version of Record published before inclusion in an issue ) If I were not a scientist, I would be a historian and clarify many mysteries in Japanese history. I like refereeing because I can send more papers to journals without feeling guilty. View Full Article (HTML)   Enhanced Article (HTML)   Get PDF (806K)

A Novel Pentadentate Redox-Active Ligand and Its Iron(III) Complexes: Electronic Structures and O2 Reactivity

Full Paper You have full text access to this content A Novel Pentadentate Redox-Active Ligand and Its Iron(III) Complexes: Electronic Structures and O 2  Reactivity Ramona Metzinger 1 ,  Dr. Serhiy Demeshko 2 and Prof. Dr. Christian Limberg 1,* Article first published online: 13 MAR 2014 DOI: 10.1002/chem.201304535 © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Article References Supporting Information Cited By View Full Article with Supporting Information (HTML)   Enhanced Article (HTML)   Get PDF (978K) Keywords: coordination chemistry; iron; O O activation; radicals; redox-active ligands Abstract A novel redox-active ligand, H 4 Ph2S L AP  ( 1 ) which was designed to be potentially pentadentate with an O,N,S,N,O donor set is described. Treatment of  1  with two equivalents of potassium hydride gave access to octametallic precursor complex [H 2 Ph2S L AP K 2 (thf)] 4  ( 2 ), w...

Unified View of Oxidative C–H Bond Cleavage and Sulfoxidation by a Nonheme Iron(IV)–Oxo Complex via Lewis Acid-Promoted Electron Transfer

Article Unified View of Oxidative C–H Bond Cleavage and Sulfoxidation by a Nonheme Iron(IV)–Oxo Complex via Lewis Acid-Promoted Electron Transfer ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView PDF  [2622 KB] PDF w/ Links [543 KB] Full Text HTML Abstract Supporting Info -> Figures Reference QuickView Add to ACS ChemWorx Jiyun Park   † ,   Yuma Morimoto   † ,  Yong-Min Lee   ‡ , Wonwoo Nam   * ‡ , and  Shunichi Fukuzumi   * † ‡ †  Department of Material and Life Science, Graduate School of Engineering,  Osaka University, ALCA ,  Japan Science and Technology Agency (JST) , Suita, Osaka 565-0871,  Japan ‡  Department of Chemistry and Nano Science, Department of Bioinspired Science,  Ewha Womans University , Seoul 120-750,  Korea Inorg. Chem. , Article ASAP DOI:  10.1021/ic403124u Publication Date (Web): March 7, 2014 Copyright © 2014 America...
Tandem C H Activation/Arylation Catalyzed by Low-Valent Iron Complexes with Bisiminopyridine Ligands Elise Salanouve,  Ghania Bouzemame,  Dr. Sébastien Blanchard,  Dr. Etienne Derat, Dr. Marine Desage-El Murr * ,  Prof. Louis Fensterbank * Article first published online: 13 MAR 2014 DOI: 10.1002/chem.201304459 © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Issue Chemistry - A European Journal Early View (Online Version of Record published before inclusion in an issue) Additional Information (Show All) How to Cite Author Information Publication History Funding Information Abstract Article References Supporting Information Cited By View Full Article with Supporting Information (HTML)   Enhanced Article (HTML)   Get PDF (1177K) Keywords: catalysis; C H activation; iron; IR spectroscopy; redox-active ligands Abstract Tandem C H activation/arylation between unactivated ...