Pankaj Kumar † , Yong-Min Lee † , Young Jun Park † , Maxime A. Siegler ‡ , Kenneth D. Karlin * ‡ , and Wonwoo Nam * † † Department of Chemistry and Nano Science, Ewha Womans University , Seoul 120-750, Korea ‡ Department of Chemistry, The Johns Hopkins University , Baltimore, Maryland 21218, United States J. Am. Chem. Soc. , 2015 , 137 (13), pp 4284–4287 DOI: 10.1021/ja513234b Publication Date (Web): March 20, 2015 Copyright © 2015 American Chemical Society * karlin@jhu.edu , * wwnam@ewha.ac.kr Abstract New Co III –nitrosyl complexes bearing N-tetramethylated cyclam (TMC) ligands, [(12-TMC)Co III (NO)] 2+ ( 1 ) and [(13-TMC)Co III (NO)] 2+ ( 2 ), were synthesized via [(TMC)Co II (CH 3 CN)] 2+ + NO(g) reactions. Spectroscopic and structural characterization showed that these compounds bind the nitrosyl moiety in...