Iron(III) complexes of tripodal tetradentate 4N ligands as functional models for catechol dioxygenases: the electronic vs. steric effect on extradiol cleavage
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C3DT52145A, Paper
Mani Balamurugan, Prabha Vadivelu, Mallayan Palaniandavar
The extradiol (E) to intradiol (I) product selectivity (E/I, 0.1-2.0) depends upon the asymmetry in bidentate coordination of catecholate, as determined by the stereoelectronic properties of the ligands. |
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