The Aldimine Effect in Bis(imino)Pyridine Complexes: Non-Planar Nickel(I) Complexes of a Bis(aldimino)pyridine Ligand

チリックらがよく用いるレドックスノンイノセント配位子 をもつニッケル錯体の一価種です。

Stanislav Groysman,   Blake R Reed,   Sebastian A Stoian and  Richard L Lord  

Chem. Commun., 2015, Accepted Manuscript

DOI: 10.1039/C5CC00203F
Received 09 Jan 2015, Accepted 27 Jan 2015
First published online 27 Jan 2015

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Reduction of bis(aldimino)pyridine nickel(II) dihalide forms a non-planar bis(aldimino)pyridine nickel(I) halide. Unlike the previously reported square-planar bis(ketimino)pyridine nickel chloride, for which the spin density was localized on the ligand, the present species demonstrate Npy-Ni-X angles of 156° – 162° and a significant spin density at the metal inferred from EPR measurements and DFT calculations.