Supramolecular Catalysis in Metal–Ligand Cluster Hosts

触媒作用を有するケージ状化合物に関する総説です。

Casey J. Brown †, F. Dean Toste *†, Robert G. Bergman *†‡, and Kenneth N. Raymond *†‡

† Department of Chemistry, University of California, Berkeley, California 94720-1460, United States

‡ Division of Chemical Sciences, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States

Chem. Rev., 2015, 115 (9), pp 3012–3035

DOI: 10.1021/cr4001226

Publication Date (Web): April 21, 2015

Copyright © 2015 American Chemical Society

*(F.D.T.) E-mail fdtoste@berkeley.edu., *(R.G.B.) E-mail rbergman@berkeley.edu., *(K.N.R.) E-mail raymond@socrates.berkeley.edu.

Table of Contents

• 1. Introduction
• 2. Early Examples of Supramolecular Hosts in Chemistry and Catalysis
• 3. Metallosupramolecular Hosts
  • 3.1. Host Design and Synthesis
  • 3.2. Stoichiometric and Catalytic Chemistry in Supramolecular Coordination Complexes
  • 3.3. Stabilization of Reactive Species within Supramolecular Coordination Cages
• 4. Transition Metal Chemistry and Catalysts in Supramolecular Hosts
• 5. Enantioselective Supramolecular Catalysts
• 6. Conclusions and Outlook

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