Ligand tuning of single-site manganese-based catalytic antioxidants with dual superoxide dismutase and catalase activity

Communication

Ligand tuning of single-site manganese-based catalytic antioxidants with dual superoxide dismutase and catalase activity

Michaela Grau,^a   Francesco Rigodanza,^b   Andrew J. P. White,^a  Antonio Sorarù,^b   Mauro Carraro,^b   Marcella Bonchio*^b and  George J. P. Britovsek*^a  

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Chem. Commun., 2014,50, 4607-4609

DOI: 10.1039/C4CC00758A
Received 28 Jan 2014, Accepted 10 Mar 2014
First published online 12 Mar 2014

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A bio-inspired manganese(II) complex with a linear pentadentate ligand framework containing soft sulfur donors and an alternating NSNSN binding motif displays excellent dual CAT/SOD-like antioxidant activity with high turnover efficiency and good operation stability in an aqueous environment.