Review You have full text access to this content Method of Continuous Variations: Applications of Job Plots to the Study of Molecular Associations in Organometallic Chemistry Dr. Joseph S. Renny, Laura L. Tomasevich, Evan H. Tallmadge, Prof. David B. Collum * DOI: 10.1002/anie.201304157 ジョブスプロットをご存知でしょうか。溶液中で、相互作用をもった二つの成分がどのような比で会合しているかを決定するためのプロット法の一つです。知っておいて、損はしません。 Abstract Applications of the method of continuous variations (MCV or the Method of Job) to problems of interest to organometallic chemists are described. MCV provides qualitative and quantitative insights into the stoichiometries underlying association of m molecules of A and n molecules of B to form A m B n . Applications to complex ensembles probe associations that form metal clusters and aggregates. Job plots in which reaction rates are monitored provide relative stoichiometries in rate-limiting transition structures. In ...