Communication

Controlling helical chirality of cobalt complexes by chirality transfer from vicinal diamines

Min-Seob Seo,^ab   Kiseong Kim^ab and   Hyunwoo Kim*^ab  

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Chem. Commun., 2013, Advance Article

DOI: 10.1039/C3CC46887A
Received 09 Sep 2013, Accepted 03 Oct 2013
First published online 16 Oct 2013

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Stereoselective cis–trans isomerism of a Co^III–N₂O₂ complex has been achieved by coordinating chiral vicinal diamines. The induced metal-centered helical chirality can be exploited for chirality amplification and asymmetric coordination chemistry.