Communication

Synthesis and Characterisation of the First Gold-Alkylperoxo Complexes

Steve Nolan,   Alexandra Slawin,   Alba Collado,  Adrian Gomez suarez and   yoshi oonishi  

Chem. Commun., 2013, Accepted Manuscript

DOI: 10.1039/C3CC47030J
Received 13 Sep 2013, Accepted 27 Sep 2013
First published online 30 Sep 2013

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The synthesis of a new class of organogold species containing a peroxo moiety is reported. Complexes [Au(IPr)(OOtBu)] and [Au(SIPr)(OOtBu)] have been synthesised via a straightforward method using the related gold hydroxide complexes as synthons.